CHEMISTRY

Course objectives

THE COURSE OF CHEMISTRY HAS A VERY EDUCATIONAL IMPORTANCE FOR ANY FACULTY OF SCIENTIFIC TECHNICAL ADDRESS. THE GENERAL OBJECTIVE IN THIS COURSE IS TO EXPLAIN THE ARGUMENTS OF GENERAL CHEMISTRY, BOTH IN EXPERIMENTAL AND THEORETICAL ASPECTS, TOGETHER WITH THE FOUNDATIONS OF INORGANIC CHEMISTRY. THE STUDENT WILL ACQUIRE THE ABILITY TO INTERCONNECT THE ARGUMENTS TREATING THE PHENOMENA RELATED TO THE BEHAVIOR OF THE MATERIALS DESCRIBED ALSO THROUGH THE PRINCIPLES OF THERMODYNAMICS. A COLLECTIVE TRAINING WILL BE PROVIDED DURING THE COURSE THROUGH WHICH STUDENTS WILL BE ABLE TO DISCUS AMONG THEM RELATIVELY TO WHAT LEARNED UNTIL THAT MOMENT, DEVELOPING IN THIS WAY EVEN COMMUNICATION SKILLS. THE STUDENT WILL BE MADE IN CONDITION OF UNDERSTANDING AND EVALUATING THE CHEMICAL, THERMODYNAMIC AND STRUCTURE ASPECTS OF THE MATERIALS RELATED TO THE SUCCESSIVE ACADEMIC COURSES. THE PROGRAM CAN BE STRUCTURED PRINCIPALLY IN 4 MODULES BELOW ILLUSTRATED TOGETHER WITH THE SPECIFIC OBJECTIVES FOR EVERYONE: 1) THE STRUCTURE OF THE MATTER - ELECTRONIC STRUCTURE OF THE ATOMS AND PERIODIC CLASSIFICATION OF THE ELEMENTS - CHEMICAL BONDS - MOLECULAR STRUCTURES AND GEOMETRIES - SUBSTANCES AND STECHIOMETRIC-CALCULATIONS - OXIDATION STATES OF ELEMENTS AND REDOX REACTIONS THE STUDENT KNOWS AND UNDERSTANDS THE STRUCTURE OF THE MATERIALS, STARTING FROM THE ATOMS AND PERIODIC CLASSIFICATION OF THE ELEMENTS AND CONSEQUENTLY HE CAN GIVE A PREDICTION ON WHICH TYPE OF CHEMICAL BOND CAN BE FORMED BETWEEN TWO CHEMICAL SPECIES AND WHICH MECHANICAL AND STRUCTURAL PROPERTY THE DERIVING COMPOSITE CAN HAVE. ACCORDINGLY, HE WILL BE ABLE TO PRODUCE, AUTONOMOUSLY, A CLASSIFICATION OF SUBSTANCES ON THE BASIS OF THE CHEMICAL BONDS AND THE PROPERTY CONNECTED TO THEM. THE STUDENT WILL ACQUIRE KNOWLEDGE ABOUT THE CONCEPTS OF STECHIOMETRIC RATIO THAT CHARACTERIZE THE MATTER AND ITS TRANSFORMATIONS AND WILL BE ABLE TO BALANCE ANY CHEMICAL REACTION BY DETERMINING THE QUANTITIES OF THE PRODUCTS KNOWING ALSO THE NON-STECHIOMETRIC QUANTITIES OF THE REAGENTS. HE WILL BE ABLE TO LEARN THE NEXT PART OF THE PROGRAM AND ALL THE CONCEPTS POTENTIALLY PRESENT IN PROGRAMS OF SUBSEQUENT COURSES. 2) THERMODYNAMICS - STATE OF MATTER AGGREGATION. 1ST AND 2ND PRINCIPLE OF THERMODYNAMICS. PHASE DIAGRAMS. - CHEMICAL EQUILIBRIUM (VAN T'HOFF EQUATION). - EQUILIBRIUM BETWEEN DIFFERENT PHASES OF NO CHEMICALLY REAGENT SUBSTANCES (CLAPEYRON EQUATION). THE STUDENT KNOWS AND UNDERSTANDS THE THERMODYNAMICS APPLIED TO THERMODYNAMIC SYSTEMS AND THROUGH THE FIRST AND SECOND PRINCIPLE OF THERMODYNAMICS HE IS ABLE TO ANALYZE BOTH THE ENERGY EXCHANGES AND TRANSFORMATIONS RESPECTIVELY WITH THE ENVIRONMENT AND INSIDE THE SYSTEM. HE IS, AUTONOMOUSLY, ABLE TO UNDERSTAND THE DIRECTION OF A TRANSFORMATION AND WHICH IS THE MAXIMUM USEFUL WORK EXTRACTABLE FROM ANY REACTIVE SYSTEM. THE STUDENT LEARNS HOW TO ANALYZE, AUTONOMOUSLY THE PHASE DIAGRAMS TO EXTRACT THE THERMODYNAMIC INFORMATION NEEDED TO INTERPRET THE SYSTEM. HE IS ABLE TO CALCULATE THE EQUILIBRIUM COMPOSITION OF A REACTIVE SYSTEM AND TO ANALYZE THE EQUILIBRIUM BETWEEN DIFFERENT PHASES OF NON-REAGENT SUBSTANCES. HE IS ABLE TO LEARN THE NEXT PART OF THE COURSE AS EQUILIBRIUMS IN SOLUTION AND ELECTROCHEMISTRY, AS WELL AS ALL THE CONCEPTS RELATED TO THERMODYNAMICS PRESENT IN THE OTHER SUBSEQUENT COURSE PROGRAMS. 3) IONIC EQUILIBRIUM IN WATER SOLUTION - SOLUTION PROPERTIES OF NON-ELECTROLYTE AND ELECTROLYTE SOLUTES - ELECTRICAL CONDUCTIVITY OF ELECTROLYTE SOLUTIONS: SPECIFIC CONDUCTIVITY, EQUIVALENT CONDUCTIVITY AND EQUIVALENT CONDUCTIVITY LIMIT. - ACID-BASE. SALTS. - BUFFER SOLUTIONS. - LOW SOLUBLE ELECTROLYTES: SOLUBILITY AND SOLUBILITY PRODUCT. THE STUDENT KNOWS AND UNDERSTANDS THE PROPERTIES OF SOLUTIONS OF NON-ELECTROLYTE AND ELECTROLYTE SOLUTIONS AS COLLIGATIVE PROPERTIES, ELECTRICAL CONDUCTIVITY AND ACID-BASE PROPERTIES. HE IS AUTONOMOUSLY ABLE TO REALIZE SOLUTION TITRATIONS, TO CALCULATE THE PH AND TO PRODUCE BUFFER SOLUTIONS TO MAINTAIN CONSTANT THE PH OF A REACTIVE AND NON-REACTIVE SYSTEM. IT IS ABLE TO STUDY AND ANALYZE HETEROGENEOUS CHEMICAL EQUILIBRIUM. ALSO IN THIS CASE HE IS ABLE TO LEARN THE NEXT PART OF THE PROGRAM AND ALL THE CONCEPTS POTENTIALLY PRESENT IN PROGRAMS OF SUBSEQUENT OTHER COURSES. 4) ELECTROCHEMISTRY AND CHEMICAL KINETICS - CONVERSION OF "CHEMICAL ENERGY" IN "ELECTRIC ENERGY" AND VICEVERSA BY ELECTROCHEMICAL DEVICES. - NERNST EQUATION. - ELECTROMOTIVE FORCE OF A GALVANIC ELEMENT. - - ELECTRODIC POTENTIAL AND ELECTRODIC STANDARD POTENTIAL OF A HALF-CELL. - STANDARD REDOX POTENTIALS TABLE OF REDUCING COUPLE, OXIDING AND REDUCING POWER OF REDOX COUPLES. - CHEMICAL KINETICS THE STUDENT KNOWS AND UNDERSTANDS THE PROPERTIES OF ELECTROCHEMICAL SYSTEMS AS PILES AND FUEL CELL OR ELECTROLYZERS CAPABLE OF CONVERTING CHEMICAL ENERGY IN ELECTRIC ENERGY OR VICE-VERSA. HE IS ABLE TO UNDERSTAND AND TO CONCEIVE ELECTROCHEMICAL SYSTEMS BY COUPLING HALF-CELLS BETWEEN THEM IN ORDER TO OBTAIN ENERGY FROM THE RESULTING SYSTEM. IN ADDITION KNOWING THE STANDARD POTENTIALS OF REDOX COUPLES HE IS ABLE TO UNDERSTAND WHETHER A REACTION THROUGH REAGENTS IS POSSIBLE OR NOT. HE KNOWS AND UNDERSTANDS THE BASIS OF CHEMICAL KINETICS. AT THE END OF THE COURSE, HE IS ABLE TO ANALYZE, IN GENERAL, ENERGY SYSTEMS FROM THERMODYNAMIC-KINETIC AND ENERGETIC POINT OF VIEW VALUATING STRENGTHS AND CRITICALITIES.

Channel 1
RITA PETRUCCI Lecturers' profile

Program - Frequency - Exams

Course program
Elements, Substances, Stoichiometric Calculations: an atom, atomic number, mass number, elements and compounds, relative atomic and molecular mass. Percent composition of a compound: minimum and molecular formula. Mole and molar mass. Stoichiometry. Electronic structure of atom and periodic classification of elements: atomic models; emission and absorption spectra. Undulatory-corpuscular model of light and matter: from Planck to de Broglie. Heisenberg's uncertainty principle. Quantum model of Bohr hydrogen atom. Quantum-wave model of the hydrogen atom: energy levels and orbitals. Electronic structure of polyelectronic atoms: the periodic table of the elements. Electronic structure and properties of the elements. Electronic affinity and ionization potential. Chemical bonds: Ionic bond. Covalent bond according to the Valence Bond theory. Electronegativity and polarity in bonds. Intermolecular bonds and states of aggregation of matter: hydrogen bond, Van der Waals forces. Molecule structure, geometry and hybridization: the VSEPR method. Resonance. The chemical bond according to the theory of Molecular Orbitals: hints - correlation diagrams for diatomic molecules, delocalized electrons bond. The metallic bond: band pattern. Conductors, semiconductors and insulators. Oxidation state of the elements and redox reactions: oxidation state of an element in a compound and variations: redox reactions. Redox balance by the oxidation number variation method. Gaseous state: ideal gas and state equation. Kinetic gas theory and Maxwell Boltzmann distribution: overview. Gaseous mixtures: molar fraction, partial pressure, gaseous density, relative density, apparent molecular mass. Real gas and Van der Waals equation. Chemical thermodynamics. Variation of energy in transformations: equivalence between heat and mechanical work, 1st principle of thermodynamics, internal energy, enthalpy, Hess law. Spontaneity of a transformation: 2nd principle of thermodynamics, entropy, free energy, chemical potential. Chemical equilibrium: phase equilibria. Pure substances: Clausius-Clapeyron equation, diagrams of water and carbon dioxide state. Non-reactive liquid-liquid mixtures: liquid-vapor equilibrium, Raoult's law and deviations. Distillation of ideal and real mixtures. Solutions and colligative properties: lowering of vapor pressure, cryoscopic lowering, elevation of the ebullioscope, osmotic pressure. Equilibrium of matter: reaction equilibria. Homogeneous and heterogeneous gaseous equilibria. Law of the masses: equilibrium constants kp and kc. Reaction progress degree. The principle of Le Chatelier. Factors that influence the composition of a system at equilibrium. Dependence of the equilibrium constant from the temperature: Van't Hoff equation. Ionic equilibria in aqueous solution. The auto-protolysis reaction of water and pH. Acids and bases according to the theory of Brønsted and Lowry. Calculation of pH for a strong (base) acid and for a weak (monoprotic) (base) acid in diluted and very diluted solutions. Salt hydrolysis. Polyprotic acids and bases. Amphoteric electrolytes. Non-reactive mixtures (dilutions) and reactive mixtures (neutralizations). Buffer solutions. Heterogeneous equilibria in aqueous solution. Less soluble salts: saturated solution, solubility, solubility product. Precipitation from solution, effect of the common ion, influence of pH on the solubility. Chemical kinetics: reaction rate. Reaction mechanism and transition state theory. Kinetic equation for first and second order reactions. Influence of temperature: Arrhenius equation. Catalysis. Electrochemistry: semireactions and balancing with the ionic-electronic method. Free energy and useful work: conversion of chemical energy into electricity. Galvanic cells. Electromotive force and Nernst equation. Reference electrodes: the standard hydrogen electrode. Table of standard potential and its applications. Galvanic corrosion, passivation. Introduction to organic chemistry: saturated and unsaturated aliphatic hydrocarbons: nomenclature, structure isomeric, conformational and geometric, reactivity. Aromatic hydrocarbons (benzene). Main functional groups: alkyl halides, alcohols, amines, aldehydes, ketones, carboxylic acids, esters and amides.
Prerequisites
No requirements requested.
Books
- Fondamenti di Chimica, M. Schiavello e L. Palmisano, 6a ed. (e-book, esercizi di ricapitolazione, guida per la risoluzione di esercizi di chimica), EdiSES - Fondamenti di Chimica per le Tecnologie, R. Bertani, M. Dettin, M. Mozzon, P. Sgarbossa, (con e-book e Software di simulazione), EdiSES - Principi di Chimica, P. Atkins e L. Jones, 4a ed. (con e-book), Zanichelli - Chimica Generale, R. H. Petrucci, F. G. Herring, J. D. Madura, C. Bissonnette, 11a ed. (con oltre 3000 esercizi), Piccin - Chimica, esercizi e casi pratici, D’Arrigo, Famulari, Gambarotti, Scotti, 4a ed.(e-book) EdiSES - Chimica Test ed Esercizi, Michelin, Sgarabossa, Mozzon, Munari, CEA (Zanichelli) - Stechiometria, G. Marcì, L. Palmisano, F. Ruffo, EdiSES
Teaching mode
Attendance is optional. The course takes place according to the following scheme: Presentation of the course about contents, self-evaluation tests, tutors, teaching and didactic material available online, textbook, examination date and procedures; Lectures, also performed through audiovisual media such as ppt presentations available online from the beginning of the course, in which the theoretical aspects y are constantly supported by exercises in the classroom with the aim of starting the students to develop a scientific method of problem-solving, to apply new knowledge, to verify acquired skills. The classroom exercises are carried out under the lecturer guidance as well as independently, also working in groups, always under the assistance of the lecturer her/himself; Carrying out self-assessment tests at the end of each cycle of topics covered (5/6 tests in the three months of the course), in the classroom, in order to allow students to check the progress of their own knowledge and skills, identify any critical issues, strengthen weaknesses ; Conducting a written exam simulation at the end of the course unit, to allow students to check their preparation for the exam and choose with greater awareness the most suitable examination data. All the material prepared during the home-teaching/e-learning for Covid-19 emergency, will be held available on Moodle platform.
Frequency
not mandatory
Exam mode
The exam consists of a written exam and an oral exam. The written exam consists on the solution of 5 exercises. A minimum grade of 15/30 is requested to access the oral exam. The oral exam, which always starts from a topic of the syllabus chosen by the student, has the main objective to verify the ability to reason on topics of a chemical nature applying the knowledge and skills acquired during the course unit. Knowledge, logic, consistency, method and appropriate language contribute to the grade assigned to the oral exam, that averaged with the written test grade produces the final grade. Two ongoing tests will be held, that might provide the exsemption from the written exam.
Lesson mode
Attendance is optional. The course takes place according to the following scheme: Presentation of the course about contents, self-evaluation tests, tutors, teaching and didactic material available online, textbook, examination date and procedures; Lectures, also performed through audiovisual media such as ppt presentations available online from the beginning of the course, in which the theoretical aspects y are constantly supported by exercises in the classroom with the aim of starting the students to develop a scientific method of problem-solving, to apply new knowledge, to verify acquired skills. The classroom exercises are carried out under the lecturer guidance as well as independently, also working in groups, always under the assistance of the lecturer her/himself; Carrying out self-assessment tests at the end of each cycle of topics covered (5/6 tests in the three months of the course), in the classroom, in order to allow students to check the progress of their own knowledge and skills, identify any critical issues, strengthen weaknesses ; Conducting a written exam simulation at the end of the course unit, to allow students to check their preparation for the exam and choose with greater awareness the most suitable examination data. Teaching material available on Moodle platform.
Channel 2
MATTEO BONOMO Lecturers' profile
  • Lesson code1015378
  • Academic year2024/2025
  • CourseClinical Engineering
  • CurriculumCurriculum unico
  • Year1st year
  • Semester2nd semester
  • SSDCHIM/07
  • CFU9
  • Subject areaFisica e chimica