Mathematical methods in quantum mechanics

Course objectives

General skills The course aims to transmit to students a deep knowledge of the mathematical structure of Quantum Mechanics, of the historical and conceptual path leading to its formulation, and of its relations with other mathematical subjects (as e.g. functional analysis, operator theory, theory of Lie groups and their unitary representations). Specific skills A) Knowledge and understanding After the conclusion of the course, successful students will know and understand the fundamental concepts of Fourier theory, the mathematical analogy between classical mechanics and geometric optics, the historical and conceptual path which led to overcome Classical Mechanics in favour of the more general Quantum Mechanics, and the mathematical structure of Quantum Theory, with a particular emphasis on dynamical aspects (time evolution) and on the analysis of the symmetries of a quantum system (representation of the symmetry group). B) Applying knowledge and understanding The general knowledge will be complemented by the application of general concepts to some specific models, and by the ability to analyze symmetries and dynamics of simple quantum systems. Specific simple systems will be analyzed in detail, including the case of a quantum particle in a linear potential, in a harmonic potential, in a uniform magnetic field, and in a Kepler potential (hydrogenoid atom). Successful students will be potentially able to apply the general concepts also to other more complex systems, including non-hydrogenoid atoms, molecules and crystalline solids. C) Making judgements The analysis of the historical and conceptual path which led to overcome Classical Mechanics in favour of the more general Quantum Mechanics will make successful students able to autonomously judge the epistemological foundations of a physical theory, and hence to understand its natural range of application and validity. This critical judgement will lead students to privilege an epistemological apophantic approach, with respect to an apodictic one. Moreover, successful students will be able to autonomously judge the validity of a mathematical statement, through a critical analysis of the hypotheses and of the deductive steps leading to the proof of the statement itself, and to autonomously formulate counterexamples to mathematical statements whenever one of the hypotheses is denied. D) Communication skills Successful students will acquire the ability to communicate what has been learned through written themes and oral exams, and to formulate a logically structured speech, with a clear distinction between hypotheses, deduction and thesis. E) Learning skills Successful students will acquire the ability to identify the most relevant topics in a subject and to make the logical connections between the topics covered.

Channel 1
DOMENICO MONACO Lecturers' profile

Program - Frequency - Exams

Course program
Review of Hamiltonian mechanics. Hamiltonian equations. Poisson brackets; commutation rules for position and momentum observables. Hamiltonian mechanics for charged particles in an external electromagnetic field. “Axioms” of classical mechanics. Brief outline of the experimental origins of quantum mechanics. Wave-particle nature of light and electron; double-slit experiment. Energy spectrum of the black body; Planck relation. De Broglie hypothesis for the electron. Mathematical physics description of quantum systems. Wave function and its probabilistic interpretation. Quantum operators of position and momentum: canonical commutation rules and uncertainty principle. Schrödinger equation. “Axioms” of quantum mechanics. Theory of unbounded self-adjoint operators on Hilbert spaces. Adjoint of an operator; self-adjointness; self-adjointness criteria. Resolvent and spectrum of a self-adjoint operator. Perturbation theory for self-adjoint operators: Kato-Rellich theorem. Spectral theorem: representation as multiplication operator for a self-adjoint operator, spectral measure, functional calculus of self-adjoint operators. Stone's theorem. Spectral decompositions; Weyl's theorem. Some solvable models of quantum mechanics. Free particle and relation to Fourier theory. Particle confined to an interval, boundary conditions. Charged quantum particle subject to a magnetic field; Landau Hamiltonian. Symmetries in quantum mechanics. Unitary and projective unitary representations. Wigner's theorem. The course also includes the presentation of one or more monographic topics such as the hydrogen atom, singular interactions or the introduction to the study of many-body quantum systems.
Prerequisites
Basic competence will be assumed in mathematical physics techniques acquired, for example, in the courses in Rational Mechanics, Mathematical Physics and Institutions of Mathematical Physics: Lagrangian and Hamiltonian description of classical mechanical systems, partial derivative equations relevant to mathematical physics, Fourier series and transform. Basic proficiency in some mathematical techniques acquired in courses in Real Analysis and Functional Analysis will also be assumed: Lp spaces (especially L2), Hilbert spaces, bounded operators on Hilbert spaces. When necessary, some of this topics will be reviewed in class. For a better appreciation of the phenomenological aspects of quantum mechanics, attendance of the relevant part of the course on Elements of Theoretical Physics is recommended.
Books
Werner O. Amrein. Hilbert Space Methods in Quantum Mechanics (EPFL Press, 2009). Brian C. Hall. Quantum Theory for Mathematicians. Vol. 267 in Graduate Text in Mathematics (Springer, 2013). Valter Moretti. Spectral Theory and Quantum Mechanics, 2nd edition. Vol. 110 in UNITEXT - La Matematica per il 3+2 (Springer, 2017). Alessandro Teta. A Mathematical Primer on Quantum Mechanics (Springer, 2018). Bernd Thaller. Visual Quantum Mechanics (Springer, 2000).
Frequency
Attendance is optional, but warmly recommended.
Exam mode
The exam consists of an oral interview on the topics covered in the course. The interview may start with the discussion of one of the exercises proposed during the course or assigned at the time. To pass the exam, the student must be able to discuss, with due mathematical rigor, topics presented in class, or to apply the methods learned to examples and situations similar to those discussed in the course. In the evaluation, consideration will be given to: - correctness, clarity, completeness and rigor in exposition; - ability to connect the various topics presented in class; - problem-solving aptitude.
Bibliography
Mathieu Lewin. Spectral Theory and Quantum Mechanics. Universitext (Springer, 2024). Michael Reed, Berry Simon. Methods of Modern Mathematical Physics. 4 volumes. Academic Press.
Lesson mode
Face-to-face lectures. Exercises assigned for individual practice.
GIULIA BASTI Lecturers' profile

Program - Frequency - Exams

Course program
Review of Hamiltonian mechanics. Hamiltonian equations. Poisson brackets; commutation rules for position and momentum observables. Hamiltonian mechanics for charged particles in an external electromagnetic field. “Axioms” of classical mechanics. Brief outline of the experimental origins of classical mechanics. Wave-particle nature of light and electron; double-slit experiment. Energy spectrum of the black body; Planck relation. De Broglie hypothesis for the electron. Mathematical physics description of quantum systems. Wave function and its probabilistic interpretation. Quantum operators of position and momentum: canonical commutation rules and uncertainty principle. Schrödinger equation. “Axioms” of quantum mechanics. Theory of unbounded self-adjoint operators on Hilbert spaces. Adjoint of an operator; self-adjointness; self-adjointness criteria. Resolvent and spectrum of a self-adjoint operator. Perturbation theory for self-adjoint operators: Kato-Rellich theorem. Spectral theorem: representation as multiplication operator for a self-adjoint operator, spectral measure, functional calculus of self-adjoint operators. Stone's theorem. Spectral decompositions; Weyl's theorem. Some solvable models of quantum mechanics. Free particle and relation to Fourier theory. Particle confined to an interval, boundary conditions. Charged quantum particle subject to a magnetic field; Landau Hamiltonian. Symmetries in quantum mechanics. Unitary and projective unitary representations. Wigner's theorem. The course also includes the presentation of one or more monographic topics such as the hydrogen atom, singular interactions or the introduction to the study of many-body quantum systems.
Prerequisites
Basic competence will be assumed in mathematical physics techniques acquired, for example, in the courses in Rational Mechanics, Mathematical Physics and Institutions of Mathematical Physics: Lagrangian and Hamiltonian description of classical mechanical systems, partial derivative equations relevant to mathematical physics, Fourier series and transform. Basic proficiency in some mathematical techniques acquired in courses in Real Analysis and Functional Analysis will also be assumed: Lp spaces (especially L2), Hilbert spaces, bounded operators on Hilbert spaces. When necessary, some of this topics will be reviewed in class. For a better appreciation of the phenomenological aspects of quantum mechanics, attendance of the relevant part of the course on Elements of Theoretical Physics is recommended.
Books
Werner O. Amrein. Hilbert Space Methods in Quantum Mechanics (EPFL Press, 2009). Brian C. Hall. Quantum Theory for Mathematicians. Vol. 267 in Graduate Text in Mathematics (Springer, 2013). Valter Moretti. Spectral Theory and Quantum Mechanics, 2nd edition. Vol. 110 in UNITEXT - La Matematica per il 3+2 (Springer, 2017). Alessandro Teta. A Mathematical Primer on Quantum Mechanics (Springer, 2018). Bernd Thaller. Visual Quantum Mechanics (Springer, 2000).
Frequency
Attendance is optional, but warmly recommended.
Exam mode
The exam consists of an oral interview on the topics covered in the course. The interview may start with the discussion of one of the exercises proposed during the course or assigned at the time. To pass the exam, the student must be able to discuss, with due mathematical rigor, topics presented in class, or to apply the methods learned to examples and situations similar to those discussed in the course. In the evaluation, consideration will be given to: - correctness, clarity, completeness and rigor in exposition; - ability to connect the various topics presented in class; - problem-solving aptitude.
Bibliography
Mathieu Lewin. Spectral Theory and Quantum Mechanics. Universitext (Springer, 2024). Michael Reed, Berry Simon. Methods of Modern Mathematical Physics. 4 volumi. Academic Press.
Lesson mode
Face-to-face lectures. Exercises assigned for individual practice.
  • Lesson code10596056
  • Academic year2025/2026
  • CourseMathematics
  • CurriculumAlgebra e Geometria
  • Year2nd year
  • Semester1st semester
  • SSDMAT/07
  • CFU6